Table Of Content1 Introduction and Overview Electrode Processes 1 2 Potentials and Thermodynamics of Cells 7 3 Kinetics of Electrode Reactions 15 4 Mass Transfer by Migration and Diffusion 21 5 Basic Potential Step methods 25 6 Potential Sweep Methods 47 7 Polarography and Pulse Voltammetry 55 8 Controlled-Curreny Techniques 61 9 Methods Involving Forced Convection-Hydrodynamic Methods 65 10 Techniques Based on Concepts of Impedance 71 11 Bulk Electrolysis Methods 83 12 Electrode Reactions With Coupled Homogeneous Chemical Reactions 95 13 Double-Layer Structure and Adsorption 103 14 Electroactive Layers and Modified Electrodes 111 15 Electrochemical Instrumentation 115 16 Scanning Probe Techniques 121 17 Spectroelectrochemistry and other Coupled Characterization Methods 123 18 Photoelectrochemistry and Electrogenerated Chemiluminescence 131 Appendices A Mathematical Methods 135 B Digital Simulations of Electrochemical Problems 143
SynopsisExtensive explanations of problems from the text Student Solutions Manual to accompany Electrochemical Methods: Fundamentals and Applications , 2nd Edition provides fully-worked solutions for the problems presented in the text., Extensive explanations of problems from the text Student Solutions Manual to accompany Electrochemical Methods: Fundamentals and Applications , 2nd Edition provides fully-worked solutions for the problems presented in the text. Extensive, in-depth explanations walk you step-by-step through each problem, and present alternative approaches and solutions where they exist. Graphs and diagrams are included as needed, and accessible language facilitates better understanding of the material. Fully aligned with the text, this manual covers thermodynamics, mass transfer, impedance, spectroelectrochemistry, and other related topics, and appendices provide detailed mathematical reference and digital simulations., Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, lä t sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.